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Thiocyanate Coordination to the {Ta<inf>6</inf>I<inf>12</inf>}<sup>2+</sup> Cluster. Preparation and Crystal Structure of [K(Dibenzo-24-Crown-8)(CH<inf>3</inf>COCH<inf>3</inf>)]<inf>2</inf>(Ph<inf>4</inf>P)<inf>2</inf>[Ta<inf>6</inf>I<inf>12</inf>(NCS)<inf>6</inf>]
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| dc.contributor.author | Shamshurin M.V. | |
| dc.contributor.author | Sukhikh T.S. | |
| dc.contributor.author | Mikhailov M.A. | |
| dc.contributor.author | Sheven D.G. | |
| dc.contributor.author | Sokolov M.N. | |
| dc.date.accessioned | 2021-02-24T20:33:05Z | |
| dc.date.available | 2021-02-24T20:33:05Z | |
| dc.date.issued | 2020 | |
| dc.identifier.issn | 0022-4766 | |
| dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/160841 | |
| dc.description.abstract | © 2020, Pleiades Publishing, Ltd. The reaction of Ta6I14 with KNCS in acetonitrile in the presence of 24-dibenzo-crown-8 leads to dissolution of the tantalum iodide cluster to form the [Ta6I12(NCS)6]4− complex. By evaporation of the solution with the subsequent treatment of the precipitate with acetone and PPh4Br, dark green single crystals of the composition [K(C24H32O8)(CH3COCH3)]2(Ph4P)2[Ta6I12(NCS)6] CH3COCH3(1) are obtained with a yield of 29%. The product is characterized by elemental analysis, IR, and mass spectra. The crystal structure is determined by the X-ray diffraction analysis. | |
| dc.relation.ispartofseries | Journal of Structural Chemistry | |
| dc.subject | clusters | |
| dc.subject | crown ethers | |
| dc.subject | iodides | |
| dc.subject | isothiocyanate complex {Ta I } 6 12 2+ | |
| dc.subject | tantalum | |
| dc.subject | X-ray diffraction analysis | |
| dc.title | Thiocyanate Coordination to the {Ta<inf>6</inf>I<inf>12</inf>}<sup>2+</sup> Cluster. Preparation and Crystal Structure of [K(Dibenzo-24-Crown-8)(CH<inf>3</inf>COCH<inf>3</inf>)]<inf>2</inf>(Ph<inf>4</inf>P)<inf>2</inf>[Ta<inf>6</inf>I<inf>12</inf>(NCS)<inf>6</inf>] | |
| dc.type | Article | |
| dc.relation.ispartofseries-issue | 5 | |
| dc.relation.ispartofseries-volume | 61 | |
| dc.collection | Публикации сотрудников КФУ | |
| dc.relation.startpage | 727 | |
| dc.source.id | SCOPUS00224766-2020-61-5-SID85089236621 |
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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.