dc.contributor.author |
Shamshurin M.V. |
|
dc.contributor.author |
Sukhikh T.S. |
|
dc.contributor.author |
Mikhailov M.A. |
|
dc.contributor.author |
Sheven D.G. |
|
dc.contributor.author |
Sokolov M.N. |
|
dc.date.accessioned |
2021-02-24T20:33:05Z |
|
dc.date.available |
2021-02-24T20:33:05Z |
|
dc.date.issued |
2020 |
|
dc.identifier.issn |
0022-4766 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/160841 |
|
dc.description.abstract |
© 2020, Pleiades Publishing, Ltd. The reaction of Ta6I14 with KNCS in acetonitrile in the presence of 24-dibenzo-crown-8 leads to dissolution of the tantalum iodide cluster to form the [Ta6I12(NCS)6]4− complex. By evaporation of the solution with the subsequent treatment of the precipitate with acetone and PPh4Br, dark green single crystals of the composition [K(C24H32O8)(CH3COCH3)]2(Ph4P)2[Ta6I12(NCS)6] CH3COCH3(1) are obtained with a yield of 29%. The product is characterized by elemental analysis, IR, and mass spectra. The crystal structure is determined by the X-ray diffraction analysis. |
|
dc.relation.ispartofseries |
Journal of Structural Chemistry |
|
dc.subject |
clusters |
|
dc.subject |
crown ethers |
|
dc.subject |
iodides |
|
dc.subject |
isothiocyanate complex {Ta I } 6 12 2+ |
|
dc.subject |
tantalum |
|
dc.subject |
X-ray diffraction analysis |
|
dc.title |
Thiocyanate Coordination to the {Ta<inf>6</inf>I<inf>12</inf>}<sup>2+</sup> Cluster. Preparation and Crystal Structure of [K(Dibenzo-24-Crown-8)(CH<inf>3</inf>COCH<inf>3</inf>)]<inf>2</inf>(Ph<inf>4</inf>P)<inf>2</inf>[Ta<inf>6</inf>I<inf>12</inf>(NCS)<inf>6</inf>] |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
5 |
|
dc.relation.ispartofseries-volume |
61 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
727 |
|
dc.source.id |
SCOPUS00224766-2020-61-5-SID85089236621 |
|