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dc.contributor.author | Pyataev A. | |
dc.contributor.author | Malikov I. | |
dc.contributor.author | Voronina E. | |
dc.contributor.author | Dulov E. | |
dc.date.accessioned | 2021-02-24T20:32:57Z | |
dc.date.available | 2021-02-24T20:32:57Z | |
dc.date.issued | 2020 | |
dc.identifier.issn | 0022-2860 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/160822 | |
dc.description.abstract | © 2019 Elsevier B.V. A partial spin transition stimulated by spontaneous symmetry breaking has been observed, for the first time, in the non-stoichiometric chalcogenide spinel FeCr2S4. A Fe2+ high spin - low spin transition HS-LS: S = 2 → S = 0 is detected below the Néel temperature TN in the magnetic subsystem corresponding to a part of the sample with deviations from stoichiometry. The fraction of diamagnetic Fe atoms increases with decreasing temperature. | |
dc.relation.ispartofseries | Journal of Molecular Structure | |
dc.subject | Jahn-teller effect | |
dc.subject | Mössbauer spectroscopy | |
dc.subject | Non-stoichiometric compound | |
dc.subject | Spin transition | |
dc.title | Mössbauer study of non-stoichiometric FeCr2S4 system | |
dc.type | Article | |
dc.relation.ispartofseries-volume | 1199 | |
dc.collection | Публикации сотрудников КФУ | |
dc.source.id | SCOPUS00222860-2020-1199-SID85071272039 |