Phosphine-catalyzed bishydrophosphorylation of electron-deficient alkynes

dc.contributor.author	Salin A.
dc.contributor.author	Il'in A.
dc.contributor.author	Faskhutdinov R.
dc.contributor.author	Fayzullin R.
dc.date.accessioned	2020-01-22T20:32:10Z
dc.date.available	2020-01-22T20:32:10Z
dc.date.issued	2019
dc.identifier.issn	0040-4020
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/157920
dc.description.abstract	© 2019 Elsevier Ltd Tertiary phosphines (n-Bu3P, Ph3P) efficiently catalyze the vicinal bis-addition of dialkyl phosphites and diaryl phosphine oxides to alkynoates though the tandem α-umpolung/β-Michael addition. This reaction offers a simple metal-free method for gram-scale preparation of practically useful bisphosphonates and bisphosphine oxides under mild conditions with high atom economy and selectivity.
dc.relation.ispartofseries	Tetrahedron
dc.subject	Bisphosphine oxide
dc.subject	Bisphosphonate
dc.subject	Conformational analysis
dc.subject	Phosphine organocatalysis
dc.subject	Tandem reaction
dc.title	Phosphine-catalyzed bishydrophosphorylation of electron-deficient alkynes
dc.type	Article
dc.relation.ispartofseries-issue	18
dc.relation.ispartofseries-volume	75
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	2676
dc.source.id	SCOPUS00404020-2019-75-18-SID85063594402

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Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.