dc.contributor.author |
Khrizanforova V. |
|
dc.contributor.author |
Fayzullin R. |
|
dc.contributor.author |
Morozov V. |
|
dc.contributor.author |
Gilmutdinov I. |
|
dc.contributor.author |
Lukoyanov A. |
|
dc.contributor.author |
Kataeva O. |
|
dc.contributor.author |
Gerasimova T. |
|
dc.contributor.author |
Katsyuba S. |
|
dc.contributor.author |
Fedushkin I. |
|
dc.contributor.author |
Lyssenko K. |
|
dc.contributor.author |
Budnikova Y. |
|
dc.date.accessioned |
2020-01-21T20:51:55Z |
|
dc.date.available |
2020-01-21T20:51:55Z |
|
dc.date.issued |
2019 |
|
dc.identifier.issn |
1861-4728 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/157809 |
|
dc.description.abstract |
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim New nickel-based complexes of 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (dpp-bian) with BF4− counterion or halide co-ligands were synthesized in THF and MeCN. The nickel(I) complexes were obtained by using two approaches: 1) electrochemical reduction of the corresponding nickel(II) precursors; and 2) a chemical comproportionation reaction. The structural features and redox properties of these complexes were investigated by using single-crystal X-ray diffraction (XRD), cyclic voltammetry (CV), and electron paramagnetic resonance (EPR) and UV/Vis spectroscopy. The influence of temperature and solvent on the structure of the nickel(I) complexes was studied in detail, and an uncommon reversible solvent-induced monomer/dimer transformation was observed. In the case of the fluoride complex, the unpaired electron was found to be localized on the dpp-bian ligand, whereas all of the other nickel complexes contained neutral dpp-bian moieties. |
|
dc.relation.ispartofseries |
Chemistry - An Asian Journal |
|
dc.subject |
cyclic voltammetry |
|
dc.subject |
dpp-bian |
|
dc.subject |
electrochemistry |
|
dc.subject |
nickel |
|
dc.subject |
reduction |
|
dc.title |
One-Electron Reduction of Acenaphthene-1,2-Diimine Nickel(II) Complexes |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
17 |
|
dc.relation.ispartofseries-volume |
14 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
2979 |
|
dc.source.id |
SCOPUS18614728-2019-14-17-SID85070327269 |
|