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One-Electron Reduction of Acenaphthene-1,2-Diimine Nickel(II) Complexes

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dc.contributor.author Khrizanforova V.
dc.contributor.author Fayzullin R.
dc.contributor.author Morozov V.
dc.contributor.author Gilmutdinov I.
dc.contributor.author Lukoyanov A.
dc.contributor.author Kataeva O.
dc.contributor.author Gerasimova T.
dc.contributor.author Katsyuba S.
dc.contributor.author Fedushkin I.
dc.contributor.author Lyssenko K.
dc.contributor.author Budnikova Y.
dc.date.accessioned 2020-01-21T20:51:55Z
dc.date.available 2020-01-21T20:51:55Z
dc.date.issued 2019
dc.identifier.issn 1861-4728
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/157809
dc.description.abstract © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim New nickel-based complexes of 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (dpp-bian) with BF4− counterion or halide co-ligands were synthesized in THF and MeCN. The nickel(I) complexes were obtained by using two approaches: 1) electrochemical reduction of the corresponding nickel(II) precursors; and 2) a chemical comproportionation reaction. The structural features and redox properties of these complexes were investigated by using single-crystal X-ray diffraction (XRD), cyclic voltammetry (CV), and electron paramagnetic resonance (EPR) and UV/Vis spectroscopy. The influence of temperature and solvent on the structure of the nickel(I) complexes was studied in detail, and an uncommon reversible solvent-induced monomer/dimer transformation was observed. In the case of the fluoride complex, the unpaired electron was found to be localized on the dpp-bian ligand, whereas all of the other nickel complexes contained neutral dpp-bian moieties.
dc.relation.ispartofseries Chemistry - An Asian Journal
dc.subject cyclic voltammetry
dc.subject dpp-bian
dc.subject electrochemistry
dc.subject nickel
dc.subject reduction
dc.title One-Electron Reduction of Acenaphthene-1,2-Diimine Nickel(II) Complexes
dc.type Article
dc.relation.ispartofseries-issue 17
dc.relation.ispartofseries-volume 14
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 2979
dc.source.id SCOPUS18614728-2019-14-17-SID85070327269


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  • Публикации сотрудников КФУ Scopus [22633]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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