The reaction of 4-(1,3,2-benzodioxaphosphol-2-yloxy)-3-tert-butylpent-4-en-2-one with hexafluoroacetone

dc.contributor.author	Mironov V.
dc.contributor.author	Baronova T.
dc.contributor.author	Dimukhametov M.
dc.contributor.author	Fayzullin R.
dc.contributor.author	Litvinov I.
dc.date.accessioned	2020-01-21T20:40:37Z
dc.date.available	2020-01-21T20:40:37Z
dc.date.issued	2019
dc.identifier.issn	0959-9436
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/157591
dc.description.abstract	© 2019 Catalytic (ZnCl2, Et3N) phosphorylation of tert-butylacetylacetone with 2-chloro-1,3,2-benzodioxaphosphole unexpectedly occurs with elimination of proton from the methyl group and leads to vinyloxyphosphole derivative, viz., 4-(1,3,2-benzodioxaphosphol-2-yloxy)-3-tert-butylpent-4-en-2-one. Its reaction with hexafluoroacetone gives a cage phosphorane as a result of subsequent chemoselective [4 + 2]- and [3 + 2]-cycloadditions with stereoselectivity above 95%.
dc.relation.ispartofseries	Mendeleev Communications
dc.title	The reaction of 4-(1,3,2-benzodioxaphosphol-2-yloxy)-3-tert-butylpent-4-en-2-one with hexafluoroacetone
dc.type	Article
dc.relation.ispartofseries-issue	5
dc.relation.ispartofseries-volume	29
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	506
dc.source.id	SCOPUS09599436-2019-29-5-SID85074095185

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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.