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Uranyl Incorporation into the Polyoxometalate Cavity. Synthesis and Characterization of [(UO<inf>2</inf>)<inf>8</inf>P<inf>8</inf>W<inf>48</inf>O<inf>184</inf>]<sup>24–</sup>
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| dc.contributor.author | Korenev V. | |
| dc.contributor.author | Abramov P. | |
| dc.contributor.author | Gushchin A. | |
| dc.contributor.author | Stass D. | |
| dc.contributor.author | Babaev V. | |
| dc.contributor.author | Rizvanov I. | |
| dc.contributor.author | Sokolov M. | |
| dc.date.accessioned | 2020-01-21T20:33:29Z | |
| dc.date.available | 2020-01-21T20:33:29Z | |
| dc.date.issued | 2019 | |
| dc.identifier.issn | 0036-0236 | |
| dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/157425 | |
| dc.description.abstract | © 2019, Pleiades Publishing, Ltd. Abstract: The reaction of uranyl nitrate with the [P8W48O184]40– polylacunary polyanion gives the [(UO2)7P8W48O184]26– (1) and [(UO2)8P8W48O184]24– (2) anions, which were isolated as potassium and ammonium salts. For K24[(UO2)8P8W48O184] · 50H2O · 3LiCl and (NH4)16H8[(UO2)8P8W48O184] · 50H2O, X-ray diffraction study was performed. The incorporation of uranyl ions into [P8W48O184]40– was confirmed by IR and Raman spectroscopy and by mass spectrometry. Electrochemical study of 2 indicated the possibility of uranium reduction to U(IV). X-ray luminescence of the potassium salts of 1 and 2 was investigated. | |
| dc.relation.ispartofseries | Russian Journal of Inorganic Chemistry | |
| dc.subject | electrochemistry | |
| dc.subject | mass spectrometry | |
| dc.subject | polyoxometalates | |
| dc.subject | uranyl | |
| dc.subject | X-ray luminescence | |
| dc.title | Uranyl Incorporation into the Polyoxometalate Cavity. Synthesis and Characterization of [(UO<inf>2</inf>)<inf>8</inf>P<inf>8</inf>W<inf>48</inf>O<inf>184</inf>]<sup>24–</sup> | |
| dc.type | Article | |
| dc.relation.ispartofseries-issue | 9 | |
| dc.relation.ispartofseries-volume | 64 | |
| dc.collection | Публикации сотрудников КФУ | |
| dc.relation.startpage | 1105 | |
| dc.source.id | SCOPUS00360236-2019-64-9-SID85073512477 |
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