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Uranyl Incorporation into the Polyoxometalate Cavity. Synthesis and Characterization of [(UO<inf>2</inf>)<inf>8</inf>P<inf>8</inf>W<inf>48</inf>O<inf>184</inf>]<sup>24–</sup>

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dc.contributor.author Korenev V.
dc.contributor.author Abramov P.
dc.contributor.author Gushchin A.
dc.contributor.author Stass D.
dc.contributor.author Babaev V.
dc.contributor.author Rizvanov I.
dc.contributor.author Sokolov M.
dc.date.accessioned 2020-01-21T20:33:29Z
dc.date.available 2020-01-21T20:33:29Z
dc.date.issued 2019
dc.identifier.issn 0036-0236
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/157425
dc.description.abstract © 2019, Pleiades Publishing, Ltd. Abstract: The reaction of uranyl nitrate with the [P8W48O184]40– polylacunary polyanion gives the [(UO2)7P8W48O184]26– (1) and [(UO2)8P8W48O184]24– (2) anions, which were isolated as potassium and ammonium salts. For K24[(UO2)8P8W48O184] · 50H2O · 3LiCl and (NH4)16H8[(UO2)8P8W48O184] · 50H2O, X-ray diffraction study was performed. The incorporation of uranyl ions into [P8W48O184]40– was confirmed by IR and Raman spectroscopy and by mass spectrometry. Electrochemical study of 2 indicated the possibility of uranium reduction to U(IV). X-ray luminescence of the potassium salts of 1 and 2 was investigated.
dc.relation.ispartofseries Russian Journal of Inorganic Chemistry
dc.subject electrochemistry
dc.subject mass spectrometry
dc.subject polyoxometalates
dc.subject uranyl
dc.subject X-ray luminescence
dc.title Uranyl Incorporation into the Polyoxometalate Cavity. Synthesis and Characterization of [(UO<inf>2</inf>)<inf>8</inf>P<inf>8</inf>W<inf>48</inf>O<inf>184</inf>]<sup>24–</sup>
dc.type Article
dc.relation.ispartofseries-issue 9
dc.relation.ispartofseries-volume 64
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 1105
dc.source.id SCOPUS00360236-2019-64-9-SID85073512477

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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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