dc.contributor.author |
Korenev V. |
|
dc.contributor.author |
Abramov P. |
|
dc.contributor.author |
Gushchin A. |
|
dc.contributor.author |
Stass D. |
|
dc.contributor.author |
Babaev V. |
|
dc.contributor.author |
Rizvanov I. |
|
dc.contributor.author |
Sokolov M. |
|
dc.date.accessioned |
2020-01-21T20:33:29Z |
|
dc.date.available |
2020-01-21T20:33:29Z |
|
dc.date.issued |
2019 |
|
dc.identifier.issn |
0036-0236 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/157425 |
|
dc.description.abstract |
© 2019, Pleiades Publishing, Ltd. Abstract: The reaction of uranyl nitrate with the [P8W48O184]40– polylacunary polyanion gives the [(UO2)7P8W48O184]26– (1) and [(UO2)8P8W48O184]24– (2) anions, which were isolated as potassium and ammonium salts. For K24[(UO2)8P8W48O184] · 50H2O · 3LiCl and (NH4)16H8[(UO2)8P8W48O184] · 50H2O, X-ray diffraction study was performed. The incorporation of uranyl ions into [P8W48O184]40– was confirmed by IR and Raman spectroscopy and by mass spectrometry. Electrochemical study of 2 indicated the possibility of uranium reduction to U(IV). X-ray luminescence of the potassium salts of 1 and 2 was investigated. |
|
dc.relation.ispartofseries |
Russian Journal of Inorganic Chemistry |
|
dc.subject |
electrochemistry |
|
dc.subject |
mass spectrometry |
|
dc.subject |
polyoxometalates |
|
dc.subject |
uranyl |
|
dc.subject |
X-ray luminescence |
|
dc.title |
Uranyl Incorporation into the Polyoxometalate Cavity. Synthesis and Characterization of [(UO<inf>2</inf>)<inf>8</inf>P<inf>8</inf>W<inf>48</inf>O<inf>184</inf>]<sup>24–</sup> |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
9 |
|
dc.relation.ispartofseries-volume |
64 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
1105 |
|
dc.source.id |
SCOPUS00360236-2019-64-9-SID85073512477 |
|