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Five new Sb(V) bromide complexes and their polybromide derivatives with pyridinium-type cations: Structures, thermal stability and features of halogen⋯halogen contacts in solid state

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dc.contributor.author Adonin S.
dc.contributor.author Bondarenko M.
dc.contributor.author Novikov A.
dc.contributor.author Plyusnin P.
dc.contributor.author Korolkov I.
dc.contributor.author Sokolov M.
dc.contributor.author Fedin V.
dc.date.accessioned 2020-01-21T20:31:05Z
dc.date.available 2020-01-21T20:31:05Z
dc.date.issued 2019
dc.identifier.issn 0020-1693
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/157315
dc.description.abstract © 2019 Elsevier B.V. Reactions of Sb2O3 solution in HBr in presence of Br2 with series of pyridinium-type cation salts resulted in formation of Cat[SbBr6] (Cat = 1,3,4-MePy+ (1) and 1,4-MePy+ (2)) and Cat2{[SbBr6](Br3)} (Cat = 1,2-MePy+ (3), 1-Et-2-MePy+ (4) and 1-Et-4-MePy+ (5)) complexes which were characterized by X-ray diffractometry. For all compounds, thermal stability was investigated by TGA method; energies of non-covalent Br⋯Br interactions were estimated by DFT calculations and QTAIM analysis (M06/DZP-DKH level of theory).
dc.relation.ispartofseries Inorganica Chimica Acta
dc.subject Antimony
dc.subject Halide complexes
dc.subject Halogen bonding
dc.subject Polyhalogens
dc.subject Supramolecular contacts
dc.title Five new Sb(V) bromide complexes and their polybromide derivatives with pyridinium-type cations: Structures, thermal stability and features of halogen⋯halogen contacts in solid state
dc.type Article
dc.collection Публикации сотрудников КФУ
dc.source.id SCOPUS00201693-2019-SID85075854928


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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