Five new Sb(V) bromide complexes and their polybromide derivatives with pyridinium-type cations: Structures, thermal stability and features of halogen⋯halogen contacts in solid state

dc.contributor.author	Adonin S.
dc.contributor.author	Bondarenko M.
dc.contributor.author	Novikov A.
dc.contributor.author	Plyusnin P.
dc.contributor.author	Korolkov I.
dc.contributor.author	Sokolov M.
dc.contributor.author	Fedin V.
dc.date.accessioned	2020-01-21T20:31:05Z
dc.date.available	2020-01-21T20:31:05Z
dc.date.issued	2019
dc.identifier.issn	0020-1693
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/157315
dc.description.abstract	© 2019 Elsevier B.V. Reactions of Sb2O3 solution in HBr in presence of Br2 with series of pyridinium-type cation salts resulted in formation of Cat[SbBr6] (Cat = 1,3,4-MePy+ (1) and 1,4-MePy+ (2)) and Cat2{[SbBr6](Br3)} (Cat = 1,2-MePy+ (3), 1-Et-2-MePy+ (4) and 1-Et-4-MePy+ (5)) complexes which were characterized by X-ray diffractometry. For all compounds, thermal stability was investigated by TGA method; energies of non-covalent Br⋯Br interactions were estimated by DFT calculations and QTAIM analysis (M06/DZP-DKH level of theory).
dc.relation.ispartofseries	Inorganica Chimica Acta
dc.subject	Antimony
dc.subject	Halide complexes
dc.subject	Halogen bonding
dc.subject	Polyhalogens
dc.subject	Supramolecular contacts
dc.title	Five new Sb(V) bromide complexes and their polybromide derivatives with pyridinium-type cations: Structures, thermal stability and features of halogen⋯halogen contacts in solid state
dc.type	Article
dc.collection	Публикации сотрудников КФУ
dc.source.id	SCOPUS00201693-2019-SID85075854928

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