Mono- and Di(dechloromethylthioylation) of Dichloromethylarenes with S-Methyl Diethylthiophosphinate

dc.contributor.author	Gazizov M.
dc.contributor.author	Valieva G.
dc.contributor.author	Ivanova S.
dc.contributor.author	Khairullin R.
dc.contributor.author	Kirillina Y.
dc.contributor.author	Antipin I.
dc.date.accessioned	2020-01-21T20:30:50Z
dc.date.available	2020-01-21T20:30:50Z
dc.date.issued	2019
dc.identifier.issn	0012-5008
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/157296
dc.description.abstract	© 2019, Pleiades Publishing, Ltd. Abstract: The attack of the thiol sulfur atom (P–SMe) on the methine carbon as the main route of the new reaction of dichloromethylarenes with S-methyl diethylthiophosphinate has been predicted and experimentally confirmed on the basis of the electronic structure of the S-alkyl esters of P(IV) acids. The processes of the mono- and di(dechloromethylthioylation) of dichloromethyl group have been realized. A new approach to the synthesis of the arenecarbaldehyde dimethyl dithioacetals has been developed avoiding the use of gaseous highly toxic methyl mercaptan.
dc.relation.ispartofseries	Doklady Chemistry
dc.title	Mono- and Di(dechloromethylthioylation) of Dichloromethylarenes with S-Methyl Diethylthiophosphinate
dc.type	Article
dc.relation.ispartofseries-issue	1
dc.relation.ispartofseries-volume	489
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	257
dc.source.id	SCOPUS00125008-2019-489-1-SID85076606403

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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.