dc.contributor.author |
Gazizov M. |
|
dc.contributor.author |
Valieva G. |
|
dc.contributor.author |
Ivanova S. |
|
dc.contributor.author |
Khairullin R. |
|
dc.contributor.author |
Kirillina Y. |
|
dc.contributor.author |
Antipin I. |
|
dc.date.accessioned |
2020-01-21T20:30:50Z |
|
dc.date.available |
2020-01-21T20:30:50Z |
|
dc.date.issued |
2019 |
|
dc.identifier.issn |
0012-5008 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/157296 |
|
dc.description.abstract |
© 2019, Pleiades Publishing, Ltd. Abstract: The attack of the thiol sulfur atom (P–SMe) on the methine carbon as the main route of the new reaction of dichloromethylarenes with S-methyl diethylthiophosphinate has been predicted and experimentally confirmed on the basis of the electronic structure of the S-alkyl esters of P(IV) acids. The processes of the mono- and di(dechloromethylthioylation) of dichloromethyl group have been realized. A new approach to the synthesis of the arenecarbaldehyde dimethyl dithioacetals has been developed avoiding the use of gaseous highly toxic methyl mercaptan. |
|
dc.relation.ispartofseries |
Doklady Chemistry |
|
dc.title |
Mono- and Di(dechloromethylthioylation) of Dichloromethylarenes with S-Methyl Diethylthiophosphinate |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
1 |
|
dc.relation.ispartofseries-volume |
489 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
257 |
|
dc.source.id |
SCOPUS00125008-2019-489-1-SID85076606403 |
|