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Electrochemical synthesis of zirconium pre-catalysts for homogeneous ethylene oligomerization

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dc.contributor.author Bekmukhamedov G.
dc.contributor.author Sukhov A.
dc.contributor.author Kuchkaev A.
dc.contributor.author Khayarov K.
dc.contributor.author Gerasimov A.
dc.contributor.author Vasilenko I.
dc.contributor.author Kostjuk S.
dc.contributor.author Yakhvarov D.
dc.date.accessioned 2020-01-15T22:10:14Z
dc.date.available 2020-01-15T22:10:14Z
dc.date.issued 2019
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/156833
dc.description.abstract © 2019 by the authors. Licensee MDPI, Basel, Switzerland. The catalytic activity of electrochemically synthesized zirconium carboxylates was studied in the process of ethylene oligomerization. Zirconium carboxylates were electrochemically synthesized directly from metallic zirconium and corresponding carboxylic acids (acetic, octanoic and lauric). A comprehensive study (element analysis, nuclear magnetic resonance (NMR) and infrared (IR) spectroscopy, powder X-ray diffraction (PXRD)) of the synthesized zirconium carboxylates showed that these species contain bidentate carboxylate moieties. It was shown that obtained zirconium carboxylates, in combination with Et3Al2Cl3 (Al/Zr = 20), have a moderate activity of (7.6–9.9) × 103 molC2H4∙molZr−1∙h−1 in terms of ethylene oligomerization (at T = 80 °C, p = 20 bar), leading to even-numbered C4–C10 linear alpha-olefins.
dc.subject Electrochemical synthesis
dc.subject Ethylene oligomerization
dc.subject Linear alpha-olefins
dc.subject Pre-catalyst
dc.subject Zirconium carboxylate
dc.title Electrochemical synthesis of zirconium pre-catalysts for homogeneous ethylene oligomerization
dc.type Article
dc.relation.ispartofseries-issue 12
dc.relation.ispartofseries-volume 9
dc.collection Публикации сотрудников КФУ
dc.source.id SCOPUS-2019-9-12-SID85077317409


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  • Публикации сотрудников КФУ Scopus [22633]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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