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Chirality control in crystalline Ni(II) complexes of thiophosphorylated thioureas

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dc.contributor.author Kataeva O.
dc.contributor.author Metlushka K.
dc.contributor.author Yamaleeva Z.
dc.contributor.author Ivshin K.
dc.contributor.author Zinnatullin R.
dc.contributor.author Nikitina K.
dc.contributor.author Sadkova D.
dc.contributor.author Badeeva E.
dc.contributor.author Sinyashin O.
dc.contributor.author Alfonsov V.
dc.date.accessioned 2020-01-15T22:10:13Z
dc.date.available 2020-01-15T22:10:13Z
dc.date.issued 2019
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/156831
dc.description.abstract © 2019 by the authors. Licensee MDPI, Basel, Switzerland. Chirality control over the formation of Ni(II) complexes with chiral thiophosphorylated thioureas was achieved via breaking the symmetry of nickel coordination geometry by the introduction of the pyridine ligand, while centrosymmetric meso-complexes are formed from racemic ligands in case of square-planar nickel coordination. Centrosymmetric heterochiral arrangement is observed in crystals of ligands themselves through N-H...S hydrogen bonds in intermolecular dimers. Molecular homochirality in tetragonal pyramidal complexes is further transferred to supramolecular homochiral arrangement via key-lock steric interactions.
dc.subject Chiral thiophosphorylated thioureas
dc.subject Chirality control
dc.subject Nickel(II) complexes
dc.subject X-ray single crystal diffraction
dc.title Chirality control in crystalline Ni(II) complexes of thiophosphorylated thioureas
dc.type Article
dc.relation.ispartofseries-issue 12
dc.relation.ispartofseries-volume 9
dc.collection Публикации сотрудников КФУ
dc.source.id SCOPUS-2019-9-12-SID85075498592


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  • Публикации сотрудников КФУ Scopus [22633]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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