Mechanism of Hydrolysis of 1,1,1-Trisubstituted Hyposilatranes and Hypogermatranes

dc.contributor.author	Vereshchagina Y.
dc.contributor.author	Ismagilova R.
dc.contributor.author	Chachkov D.
dc.date.accessioned	2020-01-15T21:46:04Z
dc.date.available	2020-01-15T21:46:04Z
dc.date.issued	2019
dc.identifier.issn	1070-4280
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/155760
dc.description.abstract	© 2019, Pleiades Publishing, Ltd. According to DFT calculations, hydrolysis of 1,1,1-trisubstituted hyposilatranes and hypogermatranes proceed in one stage and have lower activation energies than hydrolysis of the corresponding atranes and ocanes, and, unlike what is observed with the tricyclic and bicyclic analogs, the former reactions are characterized by positive Gibbs energies. The configuration of the hydrolysis products is stabilized by the transannular interactions N→X and O→X (X = Si, Ge) and intramolecular hydrogen bonding.
dc.relation.ispartofseries	Russian Journal of Organic Chemistry
dc.subject	DFT calculations
dc.subject	hydrolysis
dc.subject	hypoatranes
dc.subject	reaction mechanism
dc.title	Mechanism of Hydrolysis of 1,1,1-Trisubstituted Hyposilatranes and Hypogermatranes
dc.type	Article
dc.relation.ispartofseries-issue	2
dc.relation.ispartofseries-volume	55
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	227
dc.source.id	SCOPUS10704280-2019-55-2-SID85064940530

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