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The Reaction of Re<inf>3</inf>Br<inf>9</inf> with P(CH<inf>2</inf>OH)<inf>3</inf>: Diversity of Modes of Coordination of Hydroxymethylphosphine to Clusters
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| dc.contributor.author | Anyushin A. | |
| dc.contributor.author | Abramov P. | |
| dc.contributor.author | Sokolov M. | |
| dc.date.accessioned | 2020-01-15T21:46:00Z | |
| dc.date.available | 2020-01-15T21:46:00Z | |
| dc.date.issued | 2019 | |
| dc.identifier.issn | 1070-3284 | |
| dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/155752 | |
| dc.description.abstract | © 2019, Pleiades Publishing, Ltd. Abstract: The reaction of Re3Br9 with P(CH2OH)3 (THP) in methanol under inert atmosphere gives a new cluster complex, [Re3(µ2‑Br)3Br3(µ3-P,O,O-P(CH2OH)(CH2O)2)2H] ∙ 0.8H2O · 1.6MeOH (I). With access of air, the reaction produces a different product, [{Re3(µ2-Br)3Br2(OCH2)2PCH2-OP(CH2OH)2}2-{(P(CH2OH)(CH2O)2)}2] (II), in which two triangular clusters are linked by deprotonated THP molecules as bridging ligands. In addition, each cluster is coordinated in a tetradentate fashion by the phosphine-phosphinite ligand, resulting from the oxidative condensation of two THP molecules (CIF files CCDC 1829565 (I) and 1829566 (II)). | |
| dc.relation.ispartofseries | Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya | |
| dc.subject | clusters | |
| dc.subject | crystal structure | |
| dc.subject | hydrophilic ligands | |
| dc.subject | phosphine complexes | |
| dc.subject | rhenium | |
| dc.title | The Reaction of Re<inf>3</inf>Br<inf>9</inf> with P(CH<inf>2</inf>OH)<inf>3</inf>: Diversity of Modes of Coordination of Hydroxymethylphosphine to Clusters | |
| dc.type | Article | |
| dc.relation.ispartofseries-issue | 8 | |
| dc.relation.ispartofseries-volume | 45 | |
| dc.collection | Публикации сотрудников КФУ | |
| dc.relation.startpage | 548 | |
| dc.source.id | SCOPUS10703284-2019-45-8-SID85070477129 |
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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.