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Methyl Propiolate Cluster Complex (Ph<inf>4</inf>P)<inf>2</inf>[W<inf>6</inf>I<inf>8</inf>(C≡C–C(O)OCH<inf>3</inf>)<inf>6</inf>]

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dc.contributor.author Mikhailov M.
dc.contributor.author Abramov P.
dc.contributor.author Mironova A.
dc.contributor.author Gallyamov M.
dc.contributor.author Sheven’ D.
dc.contributor.author Pervukhin V.
dc.contributor.author Sokolov M.
dc.date.accessioned 2020-01-15T21:45:59Z
dc.date.available 2020-01-15T21:45:59Z
dc.date.issued 2019
dc.identifier.issn 1070-3284
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/155750
dc.description.abstract © 2019, Pleiades Publishing, Ltd. Abstract: A new organometallic iodide cluster complex (Bu4N)2[W6I8(C≡C–C(O)OCH3)6] (I), analogous to the previously described (Bu4N)2[Mo6I8(C≡C–C(O)OCH3)6], was obtained by the reaction of (Bu4N)2[W6I14] with silver methyl propiolate AgC≡C–C(O)OCH3. The crystal structure was established for the tetraphenylphosphonium salt (Ph4P)2[W6I8(C≡C–C(O)OCH3)6] (II). According to X-ray diffraction (CIF file CCDC no. 1829205), tungsten atoms in II are coordinated by terminal carbon atoms of methyl propiolate ligands at W–C distances of 2.220(12)–2.268(14) Å. The methyl propiolate complexes were characterized by electrospray mass spectrometry, 1H and 13C NMR spectroscopy, elemental analysis, and IR spectroscopy.
dc.relation.ispartofseries Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
dc.subject : clusters
dc.subject crystal structure
dc.subject iodides
dc.subject methyl propiolates
dc.subject organometallic compounds
dc.subject tungsten
dc.title Methyl Propiolate Cluster Complex (Ph<inf>4</inf>P)<inf>2</inf>[W<inf>6</inf>I<inf>8</inf>(C≡C–C(O)OCH<inf>3</inf>)<inf>6</inf>]
dc.type Article
dc.relation.ispartofseries-issue 1
dc.relation.ispartofseries-volume 45
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 56
dc.source.id SCOPUS10703284-2019-45-1-SID85064571214


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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