Mechanism of electrochemical reduction of 5-thio derivatives of 2(5H)-furanone

dc.contributor.author	Latypova L.
dc.contributor.author	Chmutova G.
dc.contributor.author	Kurbangalieva A.
dc.contributor.author	Yanilkin V.
dc.date.accessioned	2020-01-15T21:45:47Z
dc.date.available	2020-01-15T21:45:47Z
dc.date.issued	2019
dc.identifier.issn	1066-5285
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/155722
dc.description.abstract	© 2019, Springer Science+Business Media, Inc. The anionoid elimination of the substituent from position 5 of the lactone ring is the predominant pathway of electrochemical reduction of 5-arylsulfanyl- and 5-arylsulfonyl-3,4-dichloro-2(5H)-furanones in acetonitrile. The contribution of the competing elimination of the chloride ion increases on going to 3,4-dichloro-5-ethylsulfanyl-2(5H)-furanone. An experimental criterion based on the morphology of cyclic voltammograms was proposed for identification of a particular pathway of electroreduction of 2(5H)-furanone derivatives.
dc.relation.ispartofseries	Russian Chemical Bulletin
dc.subject	2(5H)-furanones
dc.subject	electrochemical reduction
dc.subject	mucochloric acid
dc.subject	quantum chemical calculations
dc.subject	sulfones
dc.subject	thioethers
dc.subject	voltammetry
dc.title	Mechanism of electrochemical reduction of 5-thio derivatives of 2(5H)-furanone
dc.type	Article
dc.relation.ispartofseries-issue	2
dc.relation.ispartofseries-volume	68
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	313
dc.source.id	SCOPUS10665285-2019-68-2-SID85064440535

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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.