Kazan Federal University Digital Repository

Halogen bonding in heteroleptic Cu(II) 2-iodobenzoates

Show simple item record

dc.contributor.author Adonin S.
dc.contributor.author Petrov M.
dc.contributor.author Abramov P.
dc.contributor.author Novikov A.
dc.contributor.author Sokolov M.
dc.contributor.author Fedin V.
dc.date.accessioned 2020-01-15T21:17:40Z
dc.date.available 2020-01-15T21:17:40Z
dc.date.issued 2019
dc.identifier.issn 0277-5387
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/155575
dc.description.abstract © 2019 Elsevier Ltd Reactions of [Cu4(2-IBz)4(H2O)2] with various substituted pyridines in chloroform resulted in a series of isotypic complexes [Cu2(2-IBz)4L2]·HCCl3 (2-IBz = 2-iodobenzoate, L = Py (1), 3-MePy (2), 4-MePy (3), 3-ClPy (4), 3-BrPy (5), 3,5-ClPy (6) and 3,5-MePy (7)). In all cases, halogen bonding between iodine atoms of 2-iodobenzoate units is observed; in 6, it is accompanied by Cl⋯I contacts between 3,5-ClPy and 2-IBz ligands. The energy of halogen bonding in all structures varies from 1.3 to 4.3 kcal/mol.
dc.relation.ispartofseries Polyhedron
dc.subject Carboxylates
dc.subject Copper
dc.subject Halogen bonding
dc.subject N-donor ligands
dc.subject Supramolecular contacts
dc.title Halogen bonding in heteroleptic Cu(II) 2-iodobenzoates
dc.type Article
dc.relation.ispartofseries-volume 171
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 312
dc.source.id SCOPUS02775387-2019-171-SID85072687137


Files in this item

This item appears in the following Collection(s)

  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

Show simple item record

Search DSpace


Advanced Search

Browse

My Account

Statistics