Halogen bonding in heteroleptic Cu(II) 2-iodobenzoates

dc.contributor.author	Adonin S.
dc.contributor.author	Petrov M.
dc.contributor.author	Abramov P.
dc.contributor.author	Novikov A.
dc.contributor.author	Sokolov M.
dc.contributor.author	Fedin V.
dc.date.accessioned	2020-01-15T21:17:40Z
dc.date.available	2020-01-15T21:17:40Z
dc.date.issued	2019
dc.identifier.issn	0277-5387
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/155575
dc.description.abstract	© 2019 Elsevier Ltd Reactions of [Cu4(2-IBz)4(H2O)2] with various substituted pyridines in chloroform resulted in a series of isotypic complexes [Cu2(2-IBz)4L2]·HCCl3 (2-IBz = 2-iodobenzoate, L = Py (1), 3-MePy (2), 4-MePy (3), 3-ClPy (4), 3-BrPy (5), 3,5-ClPy (6) and 3,5-MePy (7)). In all cases, halogen bonding between iodine atoms of 2-iodobenzoate units is observed; in 6, it is accompanied by Cl⋯I contacts between 3,5-ClPy and 2-IBz ligands. The energy of halogen bonding in all structures varies from 1.3 to 4.3 kcal/mol.
dc.relation.ispartofseries	Polyhedron
dc.subject	Carboxylates
dc.subject	Copper
dc.subject	Halogen bonding
dc.subject	N-donor ligands
dc.subject	Supramolecular contacts
dc.title	Halogen bonding in heteroleptic Cu(II) 2-iodobenzoates
dc.type	Article
dc.relation.ispartofseries-volume	171
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	312
dc.source.id	SCOPUS02775387-2019-171-SID85072687137

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Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.