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Electrochemical Synthesis of Zirconium Pre-Catalysts for Homogeneous Ethylene Oligomerization

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dc.contributor Казанский федеральный университет
dc.contributor.author Bekmuhamedov Giyaz Eduardovich
dc.contributor.author Sukhov Aleksandr Vyacheslavovich
dc.contributor.author Kuchkaev Aydar Maratovich
dc.contributor.author Khayarov Khasan Rafaelevich
dc.contributor.author Gerasimov Alexander Vladimirovich
dc.contributor.author Vasilenko Irina Vladimirovna
dc.contributor.author Kostyuk Sergey Viktorovich
dc.contributor.author Yakhvarov Dmitry Grigorevich
dc.date.accessioned 2019-12-18T08:10:42Z
dc.date.available 2019-12-18T08:10:42Z
dc.date.issued 2019
dc.identifier.citation Bekmukhamedov G.E. Electrochemical Synthesis of Zirconium Pre-Catalysts for Homogeneous Ethylene Oligomerization / G.E. Bekmukhamedov; A.V. Sukhov; A.M. Kuchkaev; K.R. Khayarov; A.V. Gerasimov; I.V. Vasilenko; S.V. Kostjuk; D.G. Yakhvarov // Catalysts. - 2019. - V. 9. - № 12. - P. 1059-1059..
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/152060
dc.description.abstract The catalytic activity of electrochemically synthesized zirconium carboxylates was studied in the process of ethylene oligomerization. Zirconium carboxylates were electrochemically synthesized directly from metallic zirconium and corresponding carboxylic acids (acetic, octanoic and lauric). A comprehensive study (element analysis, nuclear magnetic resonance (NMR) and infrared (IR) spectroscopy, powder X-ray diffraction (PXRD)) of the synthesized zirconium carboxylates showed that these species contain bidentate carboxylate moieties. It was shown that obtained zirconium carboxylates, in combination with Et3Al2Cl3 (Al/Zr = 20), have a moderate activity of (7.6-9.9) × 103 molC2H4⋅molZr-1⋅h-1 in terms of ethylene oligomerization (at T = 80 ?C, p = 20 bar), leading to even-numbered C4-C10 linear alpha-olefins.
dc.language.iso en
dc.relation.ispartofseries Catalysts
dc.rights открытый доступ
dc.subject electrochemical synthesis
dc.subject zirconium carboxylate
dc.subject ethylene oligomerization
dc.subject pre-catalyst
dc.subject linear alpha-olefins
dc.subject.other Химия
dc.title Electrochemical Synthesis of Zirconium Pre-Catalysts for Homogeneous Ethylene Oligomerization
dc.type Article
dc.contributor.org Химический институт им. А.М. Бутлерова
dc.description.pages 1059-1059
dc.relation.ispartofseries-issue 12
dc.relation.ispartofseries-volume 9
dc.pub-id 216672
dc.identifier.doi 10.3390/catal9121059


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