dc.contributor.author |
Litvinov I. |
|
dc.contributor.author |
Efimov S. |
|
dc.contributor.author |
Musin R. |
|
dc.contributor.author |
Klochkov V. |
|
dc.contributor.author |
Mironov V. |
|
dc.date.accessioned |
2019-01-22T20:56:24Z |
|
dc.date.available |
2019-01-22T20:56:24Z |
|
dc.date.issued |
2018 |
|
dc.identifier.issn |
2052-4110 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/149530 |
|
dc.description.abstract |
© 2018 the Partner Organisations. The reaction of 2-(1-phenylvinyloxy)benzo-1,3,2-dioxaphosphole with hexafluoroacetone, ethyltrifluoropyruvate and chloral leads to the formation of cage phosphoranes possessing the 1-phospha-2,6,8-trioxabicyclo[3.2.1]octane framework whose structure was established by the XRD method and NMR spectroscopy. The process involves dihetero-Diels-Alder and Huisgen 1,3-dipolar cycloaddition reactions and is accompanied by the simultaneous formation of the P-C and C-C bonds. Despite the generation of three chiral carbon atoms, the stereoselectivity of the process exceeds 96%. Hydrolysis leads to the formation of functionalized aldols and phosphonates. |
|
dc.relation.ispartofseries |
Organic Chemistry Frontiers |
|
dc.title |
Tandem dihetero-Diels-Alder and Huisgen cycloaddition reactions. Synthesis, crystal structure and hydrolysis of the novel cage phosphoranes |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
21 |
|
dc.relation.ispartofseries-volume |
5 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
3113 |
|
dc.source.id |
SCOPUS20524110-2018-5-21-SID85055508150 |
|