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Hybrid multicyclophanes based on thiacalix[4]arene and pillar[5]arene: Synthesis and influence on the formation of polyaniline

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dc.contributor.author Shurpik D.
dc.contributor.author Yakimova L.
dc.contributor.author Gorbachuk V.
dc.contributor.author Sevastyanov D.
dc.contributor.author Padnya P.
dc.contributor.author Bazanova O.
dc.contributor.author Rizvanov I.
dc.contributor.author Stoikov I.
dc.date.accessioned 2019-01-22T20:56:23Z
dc.date.available 2019-01-22T20:56:23Z
dc.date.issued 2018
dc.identifier.issn 2052-4110
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/149529
dc.description.abstract © 2018 the Partner Organisations. For the first time, fragments of a pillar[5]arene were spatially preorganized with a thiacalix[4]arene core in a single multimacrocyclic structure. It was shown that the synthesized hybrid multicyclophanes bind aniline and do not interact with p-toluenesulfonic acid. Supramolecular assistance of the synthesized multicyclophanes in oxidative polymerization of aniline in aqueous p-toluenesulfonic acid solutions was studied. It was found that the use of the multicyclophane template in the reaction of the oxidative polymerization of aniline led to the formation of emeraldine with a higher molecular weight and a similar conductivity (1-2 mSm cm-1), which formed more stable emeraldine dispersions in acetone in comparison with traditionally obtained polyaniline.
dc.relation.ispartofseries Organic Chemistry Frontiers
dc.title Hybrid multicyclophanes based on thiacalix[4]arene and pillar[5]arene: Synthesis and influence on the formation of polyaniline
dc.type Article
dc.relation.ispartofseries-issue 19
dc.relation.ispartofseries-volume 5
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 2780
dc.source.id SCOPUS20524110-2018-5-19-SID85053880857


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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