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Synthesis of water-soluble amino functionalized multithiacalix[4]arene via quaternization of tertiary amino groups

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dc.date.accessioned 2019-01-22T20:53:46Z
dc.date.available 2019-01-22T20:53:46Z
dc.date.issued 2018
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/149314
dc.description.abstract © 2018 by the authors. A convenient approach to the synthesis of multithiacalix[4]arene derivatives containing amino groups and phthalimide fragments by the formation of quaternary ammonium salts is presented. As the initial macrocycle for the synthesis of multithiacalix[4]arenes, a differently substituted p-tert-butylthiacalix[4]arene containing bromoacetamide and three phthalimide fragments was used in a 1,3-alternate conformation. The macrocycle in cone conformation containing the tertiary amino groups was found to be a convenient core for the multithiacalix[4]arene systems. Interaction of the core multithiacalix[4]arene with monobromoacetamide derivatives of p-tert-butylthiacalix[4]arene resulted in formation in high yields of pentakisthiacalix[4]arene containing quaternary ammonium and phthalimide fragments. The removal of phthalimide groups led to the formation of amino multithiacalix[4]arene in a good yield. Based on dynamic light scattering, it was shown that the synthesized amino multithiacalix[4]arene, with pronounced hydrophobic and hydrophilic fragments, formed dendrimer-like nanoparticles in water via direct supramolecular self-assembly.
dc.subject Aggregation
dc.subject Amino derivatives
dc.subject Dendrimers
dc.subject Multithiacalix[4]arene
dc.subject Nanoparticles
dc.subject Receptor
dc.subject Self-assembly
dc.subject Thiacalix[4]arene
dc.title Synthesis of water-soluble amino functionalized multithiacalix[4]arene via quaternization of tertiary amino groups
dc.type Article
dc.relation.ispartofseries-issue 5
dc.relation.ispartofseries-volume 23
dc.collection Публикации сотрудников КФУ
dc.source.id SCOPUS-2018-23-5-SID85046654073


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  • Публикации сотрудников КФУ Scopus [22633]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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