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Molecular tectonics: High dimensional coordination networks based on methylenecarboxylate-appended tetramercaptothiacalix[4]arene in the 1,3-alternate conformation

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dc.date.accessioned 2019-01-22T20:53:37Z
dc.date.available 2019-01-22T20:53:37Z
dc.date.issued 2018
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/149299
dc.description.abstract © 2018 The Royal Society of Chemistry. The combination, under mild conditions, of the methylenecarboxylic-appended tetramercaptotetrathiacalix[4]arene (TMTCA) derivative 4, blocked in the 1,3-alternate conformation, with acetate salts of octahedral copper(ii), manganese(ii), nickel(ii) and zinc(ii) leads to the formation, in the crystalline state, of high dimensional coordination networks. Depending on the nature of the used metal cations and bases (pyridine or non-coordinating Et3N), six new different high-dimensional coordination polymers have been evidenced, presenting 4 different coordination patterns. All the compounds present a metal/4 ratio equal to 2/1. The formation of a 2D grid-like compound (4-Zn2(Py)4) and three different pseudodiamondoid-like 3D compounds (4-Co2(Py)6(H2O)2, 4-Ni2(Py)6(H2O)2, 4-Mn2(Py)4(MeOH)2, 4-Mn2(DMF)2(MeOH)4 and 4-Zn2(MeOH)4) is observed.
dc.title Molecular tectonics: High dimensional coordination networks based on methylenecarboxylate-appended tetramercaptothiacalix[4]arene in the 1,3-alternate conformation
dc.type Article
dc.relation.ispartofseries-issue 8
dc.relation.ispartofseries-volume 20
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 1130
dc.source.id SCOPUS-2018-20-8-SID85042383653


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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