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W-Band ENDOR of Light-Induced PPerAcr Anion Radicals in Double-Crystalline Donor-Bridge-Acceptor P3HT- b -PPerAcr Block Copolymer in Frozen Solution: Experimental and DFT Study

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dc.contributor.author Konkin A.
dc.contributor.author Ritter U.
dc.contributor.author Mamin G.
dc.contributor.author Orlinskii S.
dc.contributor.author Gafurov M.
dc.contributor.author Aganov A.
dc.contributor.author Klochkov V.
dc.contributor.author Lohwasser R.
dc.contributor.author Thelakkat M.
dc.contributor.author Hoppe H.
dc.contributor.author Scharff P.
dc.date.accessioned 2019-01-22T20:51:08Z
dc.date.available 2019-01-22T20:51:08Z
dc.date.issued 2018
dc.identifier.issn 1932-7447
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/149097
dc.description.abstract © 2018 American Chemical Society. Light-induced W-band electron nuclear double resonance and density functional theory of a spin density distribution study of poly-perylene bisimide acrylate (PPerAcr) anion radicals in double-crystalline donor-bridge-acceptor block copolymers (BCPs) are under consideration. Evidence of spin density sharing in the electron acceptor block, mainly distributed on the perylenediimide frame of PPerAcr without delocalization along the π-stack direction of the PPerAcr block in BCPs, was found at the low (50 K) temperature in frozen o-1,2-dichlorobenzene solution. The electron-hopping frequency between the anion and the nearby neutral PPerAcr of assembled π-stacks in P3HT-b-PPerAcr BCPs is limited by a frequency of around 108 Hz at temperatures below 50 K in the steady-state regime of continuous-wave light illumination.
dc.relation.ispartofseries Journal of Physical Chemistry C
dc.title W-Band ENDOR of Light-Induced PPerAcr Anion Radicals in Double-Crystalline Donor-Bridge-Acceptor P3HT- b -PPerAcr Block Copolymer in Frozen Solution: Experimental and DFT Study
dc.type Article
dc.relation.ispartofseries-issue 40
dc.relation.ispartofseries-volume 122
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 22829
dc.source.id SCOPUS19327447-2018-122-40-SID85054378438


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  • Публикации сотрудников КФУ Scopus [22633]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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