(Et<inf>4</inf>N)[Mo<sup>III</sup>(DAPBH)Cl<inf>2</inf>], the first pentagonal-bipyramidal Mo(iii) complex with a N<inf>3</inf>O<inf>2</inf>-type Schiff-base ligand: manifestation of unquenched orbital momentum and Ising-type magnetic anisotropy

dc.date.accessioned	2019-01-22T20:45:35Z
dc.date.available	2019-01-22T20:45:35Z
dc.date.issued	2018
dc.identifier.issn	1359-7345
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/148627
dc.description.abstract	© The Royal Society of Chemistry. The first paramagnetic pentagonal-bipyramidal complex of Mo(iii) with a N3O2-type Schiff-base ligand was synthesized by the comproportionation reaction between Mo(ii) and Mo(iv) congeners. The complex has a low-spin (S = 1/2) ground state of MoIII(4d3) with double orbital degeneracy and unquenched orbital momentum, which result in strong Ising-type magnetic anisotropy.
dc.relation.ispartofseries	Chemical Communications
dc.title	(Et<inf>4</inf>N)[Mo<sup>III</sup>(DAPBH)Cl<inf>2</inf>], the first pentagonal-bipyramidal Mo(iii) complex with a N<inf>3</inf>O<inf>2</inf>-type Schiff-base ligand: manifestation of unquenched orbital momentum and Ising-type magnetic anisotropy
dc.type	Article
dc.relation.ispartofseries-issue	72
dc.relation.ispartofseries-volume	54
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	10084
dc.source.id	SCOPUS13597345-2018-54-72-SID85053137633

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Публикации сотрудников КФУ Scopus [24551]
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