dc.date.accessioned |
2019-01-22T20:43:15Z |
|
dc.date.available |
2019-01-22T20:43:15Z |
|
dc.date.issued |
2018 |
|
dc.identifier.issn |
1144-0546 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/148439 |
|
dc.description.abstract |
© 2018 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique. The results of a quantitative reading of the cyclic voltammetry behavior of the tryptophan (Trp) enantiomers deposited on an electrochemically activated glassy carbon electrode (GCE) are presented. A combined method for "reading" the analytical signals based on the modified Fourier transform and GPCA was applied. It allows a quantitative description of a derivative (dJ/dU) of the measured VAG. This combined method essentially increases the limits of conventional PCA and can be applied to a wide set of electrochemical data. This combined method allows the differentiation and quantitative description of signals governed by the different structures of l- and d-Trp(s) in aqueous solutions. |
|
dc.relation.ispartofseries |
New Journal of Chemistry |
|
dc.title |
Temporal multi-sensor system for voltammetric recognition of l- and d-tryptophan enantiomers based on generalized principal component analysis |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
1 |
|
dc.relation.ispartofseries-volume |
42 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
465 |
|
dc.source.id |
SCOPUS11440546-2018-42-1-SID85038833609 |
|