dc.contributor.author |
Kiselev V. |
|
dc.contributor.author |
Kornilov D. |
|
dc.contributor.author |
Anikin O. |
|
dc.contributor.author |
Plemenkov V. |
|
dc.contributor.author |
Konovalov A. |
|
dc.date.accessioned |
2019-01-22T20:42:33Z |
|
dc.date.available |
2019-01-22T20:42:33Z |
|
dc.date.issued |
2018 |
|
dc.identifier.issn |
1070-4280 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/148380 |
|
dc.description.abstract |
© 2018, Pleiades Publishing, Ltd. The effects of temperature, solvent nature, and high hydrostatic pressure on the rate of the ene reaction of 4-phenyl-3H-1,2,4-triazole-3,5(4H)-dione with β-pinene have been studied. The reaction gives only one product and is accompanied by a large heat effect. Comparison of the activation and reaction volumes indicates cyclic structure of the transition state. The reaction rate changes by a factor of 200 in the series of nine examined solvents, but this variation is not determined by solvent polarity. |
|
dc.relation.ispartofseries |
Russian Journal of Organic Chemistry |
|
dc.title |
Ene Reaction of β-Pinene with 4-Phenyl-3H-1,2,4-triazole-3,5(4H)-dione: Effects of Temperature, High Pressure, and Solvent Nature |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
7 |
|
dc.relation.ispartofseries-volume |
54 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
1080 |
|
dc.source.id |
SCOPUS10704280-2018-54-7-SID85052856810 |
|