Mechanism of Hydrolysis of 2,2-Disubstituted Silocanes and Germocanes and 1-Substituted Silatranes and Germatranes

dc.date.accessioned	2019-01-22T20:42:27Z
dc.date.available	2019-01-22T20:42:27Z
dc.date.issued	2018
dc.identifier.issn	1070-4280
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/148377
dc.description.abstract	© 2018, Pleiades Publishing, Ltd. According to DFT quantum chemical calculations, hydrolysis of 2,2-disubstituted silocanes and germocanes is characterized by lower energies of activation and slightly lower positive Gibbs energies than the hydrolysis of the corresponding silatranes and germatranes. The annular configuration of the hydrolysis products is stabilized by the transannular interaction N→X (X = Si, Ge) and intramolecular hydrogen bonding.
dc.relation.ispartofseries	Russian Journal of Organic Chemistry
dc.title	Mechanism of Hydrolysis of 2,2-Disubstituted Silocanes and Germocanes and 1-Substituted Silatranes and Germatranes
dc.type	Article
dc.relation.ispartofseries-issue	3
dc.relation.ispartofseries-volume	54
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	490
dc.source.id	SCOPUS10704280-2018-54-3-SID85048087577

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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.