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Stabilization of Hydroxy Tautomeric Form of Dimethyl Phosphite in the Coordination Sphere of Carbonyl Complexes of Group VI Metals
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| dc.contributor.author | Plotnikova A. | |
| dc.contributor.author | Kuramshin A. | |
| dc.contributor.author | Kolpakova E. | |
| dc.contributor.author | Galkin V. | |
| dc.date.accessioned | 2019-01-22T20:42:23Z | |
| dc.date.available | 2019-01-22T20:42:23Z | |
| dc.date.issued | 2018 | |
| dc.identifier.issn | 1070-3632 | |
| dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/148371 | |
| dc.description.abstract | © 2018, Pleiades Publishing, Ltd. The interaction of dimethyl phosphite with hexacarbonyls of the chromium group metals in a nonpolar solvent has afforded metal(0) σ4,λ4-(dimethyl phosphite)pentacarbonyls containing a hydroxy tautomeric form of dimethyl phosphite in the coordination sphere. Hydrogen of the phosphite OH group in the metal(0) σ4,λ4-(dimethyl phosphite)pentacarbonyls exhibited a significant acidity, strongest for the chromium complexes. Due to the significant acidity of the phosphite hydroxyl, the metal(0) σ4,λ4-(dimethyl phosphite)-pentacarbonyls are intermediates in the electrophilic version of the Pudovik reaction. | |
| dc.relation.ispartofseries | Russian Journal of General Chemistry | |
| dc.subject | chromium group metals | |
| dc.subject | metal(0) σ ,λ -(dimethyl phosphite)pentacarbonyls 4 4 | |
| dc.subject | metal(0) σ ,λ -(dimethyl phosphite)pentacarbonyls 4 5 | |
| dc.subject | outer sphere hydrophosphorylation | |
| dc.subject | phosphaorganometallic compounds | |
| dc.subject | phosphonates | |
| dc.title | Stabilization of Hydroxy Tautomeric Form of Dimethyl Phosphite in the Coordination Sphere of Carbonyl Complexes of Group VI Metals | |
| dc.type | Article | |
| dc.relation.ispartofseries-issue | 9 | |
| dc.relation.ispartofseries-volume | 88 | |
| dc.collection | Публикации сотрудников КФУ | |
| dc.relation.startpage | 1880 | |
| dc.source.id | SCOPUS10703632-2018-88-9-SID85056655853 |
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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.