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Complex Formation of 1,5-Bis(amidomethylsulfonyl)pentane with Copper(II) and Iron(III)

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dc.date.accessioned 2019-01-22T20:42:17Z
dc.date.available 2019-01-22T20:42:17Z
dc.date.issued 2018
dc.identifier.issn 1070-3632
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/148363
dc.description.abstract © 2018, Pleiades Publishing, Ltd. The state of the new antitubercular agent 1,5-bis(amidomethylsulfonyl)pentane in aqueous micellar solution of the nonionic surfactant Bridge 35 and its complexing properties toward copper(II) and iron(III) ions have been studied by spectrophotometry, pH potentiometry (25°C, variable ionic strength), and mathematical modeling. In the concentration range from 5.00 × 10–5 to 1.00 × 10–3 M in the presence of Bridge 35, the title compound exists in a neutral monomeric form. It forms 1: 2 mononuclear and 2: 2 binuclear complexes with copper(II) and 1: 1 and 1: 2 mononuclear and 2: 1 binuclear complexes with iron(III). The most favorable structures of 1,5-bis(amidomethylsulfonyl)pentane and its complexes have been simulated in terms of the density functional theory.
dc.relation.ispartofseries Russian Journal of General Chemistry
dc.subject 1,5-bis(amidomethylsulfonyl)pentane
dc.subject complex formation
dc.subject copper(II)
dc.subject iron(III)
dc.subject ligand denticity
dc.title Complex Formation of 1,5-Bis(amidomethylsulfonyl)pentane with Copper(II) and Iron(III)
dc.type Article
dc.relation.ispartofseries-issue 8
dc.relation.ispartofseries-volume 88
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 1672
dc.source.id SCOPUS10703632-2018-88-8-SID85055937319


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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