Reactions of Unsaturated Ketones with Bis(trimethylsilyl) Hypophosphite

dc.date.accessioned	2019-01-22T20:42:11Z
dc.date.available	2019-01-22T20:42:11Z
dc.date.issued	2018
dc.identifier.issn	1070-3632
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/148353
dc.description.abstract	© 2018, Pleiades Publishing, Ltd. Bis(trimethylsilyl) hypophosphite reacts with unsaturated ketones (methyl vinyl ketone and mesityl oxide) to give, depending on the reaction conditions, 1: 1 or 1: 2 adducts after hydrolysis. It was found that the intramolecular cyclization of the 1: 2 reaction product with mesityl oxide, trimethylsilyl bis(2-methyl-4- oxopentan-2-yl)phosphinate, yields, after hydrolysis, a phosphorinane with exocyclic carbonyl and hydroxyl groups.
dc.relation.ispartofseries	Russian Journal of General Chemistry
dc.subject	bis(3-oxobutyl)phosphinic acid
dc.subject	bis(trimethylsilyl) hypophosphite
dc.subject	mesityl oxide
dc.subject	methyl vinyl ketone
dc.subject	phosphorinane
dc.title	Reactions of Unsaturated Ketones with Bis(trimethylsilyl) Hypophosphite
dc.type	Article
dc.relation.ispartofseries-issue	1
dc.relation.ispartofseries-volume	88
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	90
dc.source.id	SCOPUS10703632-2018-88-1-SID85042864334

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