Thermodynamics of Imidazolium-Based Ionic Liquids Containing the Trifluoromethanesulfonate Anion

dc.date.accessioned	2019-01-22T20:38:39Z
dc.date.available	2019-01-22T20:38:39Z
dc.date.issued	2018
dc.identifier.issn	0930-7516
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/148095
dc.description.abstract	© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim A thermochemical investigation of the series of 1-alkyl-3-methylimidazolium ionic liquids (ILs) with the trifluromethanesulfonate CF3SO3− anion is presented. Absolute vapor pressures and vaporization enthalpies were measured by using a quartz crystal microbalance (QCM). The enthalpies of solutions were determined by solution calorimetry. Gas-phase enthalpies of the formation of ILs were calculated by applying the high-level quantum-chemical method G3MP2. From a combination of experimental and theoretical results, the enthalpy of formation of aqueous CF3SO3− anion was derived for the first time.
dc.relation.ispartofseries	Chemical Engineering and Technology
dc.subject	Enthalpy of formation
dc.subject	Enthalpy of vaporization
dc.subject	Ionic liquids
dc.subject	Thermodynamics
dc.subject	Vapor pressure
dc.title	Thermodynamics of Imidazolium-Based Ionic Liquids Containing the Trifluoromethanesulfonate Anion
dc.type	Article
dc.relation.ispartofseries-issue	8
dc.relation.ispartofseries-volume	41
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	1604
dc.source.id	SCOPUS09307516-2018-41-8-SID85047903357

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