dc.date.accessioned |
2019-01-22T20:38:39Z |
|
dc.date.available |
2019-01-22T20:38:39Z |
|
dc.date.issued |
2018 |
|
dc.identifier.issn |
0930-7516 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/148095 |
|
dc.description.abstract |
© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim A thermochemical investigation of the series of 1-alkyl-3-methylimidazolium ionic liquids (ILs) with the trifluromethanesulfonate CF3SO3− anion is presented. Absolute vapor pressures and vaporization enthalpies were measured by using a quartz crystal microbalance (QCM). The enthalpies of solutions were determined by solution calorimetry. Gas-phase enthalpies of the formation of ILs were calculated by applying the high-level quantum-chemical method G3MP2. From a combination of experimental and theoretical results, the enthalpy of formation of aqueous CF3SO3− anion was derived for the first time. |
|
dc.relation.ispartofseries |
Chemical Engineering and Technology |
|
dc.subject |
Enthalpy of formation |
|
dc.subject |
Enthalpy of vaporization |
|
dc.subject |
Ionic liquids |
|
dc.subject |
Thermodynamics |
|
dc.subject |
Vapor pressure |
|
dc.title |
Thermodynamics of Imidazolium-Based Ionic Liquids Containing the Trifluoromethanesulfonate Anion |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
8 |
|
dc.relation.ispartofseries-volume |
41 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
1604 |
|
dc.source.id |
SCOPUS09307516-2018-41-8-SID85047903357 |
|