dc.contributor.author |
Laricheva Y. |
|
dc.contributor.author |
Gushchin A. |
|
dc.contributor.author |
Abramov P. |
|
dc.contributor.author |
Sokolov M. |
|
dc.date.accessioned |
2019-01-22T20:36:31Z |
|
dc.date.available |
2019-01-22T20:36:31Z |
|
dc.date.issued |
2018 |
|
dc.identifier.issn |
0277-5387 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/147947 |
|
dc.description.abstract |
© 2018 Elsevier Ltd New cuboidal cluster complexes of general formula [Mo3S4(M′X)Cl3L3]0/+(M′ = Ni0, Pd0; L = dnbpy – 4,4′-dinonyl-2,2′-bipyridine or dbbpy – 4,4′-di-tert-butyl-2,2′-bipyridine; X = tu, Cl) were synthesized by reactions of trinuclear precursors [Mo3S4Cl3L3]+with Ni(COD)2(COD = 1,5-cyclooctadiene) or Pd2(dba)3·CHCl3(dba = dibenzylideneacetone) in the presence of thiourea (tu) in good yields. The complexes were characterized by elemental analysis, IR,1H NMR and ESI-MS techniques. Crystal structures of [Mo3S4(Nitu)Cl3(dbbpy)3]Cl·tu (1a), [Mo3S4(Nitu)Cl3(dbbpy)3]Cl (1b) and [Mo3S4(Pdtu)Cl3(dbbpy)3]Cl (2) were determined by X-ray analysis. The DFT calculations of the electronic structure of [Mo3S4(Pd′X)Cl3(bpy)3]0/+(X = Cl or tu) were carried out. |
|
dc.relation.ispartofseries |
Polyhedron |
|
dc.subject |
2,2′-bipyridine |
|
dc.subject |
Cubane-type clusters |
|
dc.subject |
Molybdenum |
|
dc.subject |
Nickel |
|
dc.subject |
Palladuim |
|
dc.title |
Novel mixed-metal cubane-type {Mo<inf>3</inf>NiS<inf>4</inf>} and {Mo<inf>3</inf>PdS<inf>4</inf>} clusters coordinated with 2,2′-bipyridine type ligands |
|
dc.type |
Article |
|
dc.relation.ispartofseries-volume |
154 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
202 |
|
dc.source.id |
SCOPUS02775387-2018-154-SID85051365793 |
|