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Novel non-covalent supramolecular systems based on zinc(II) bis(dipyrromethenate)s with fullerenes

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dc.contributor.author Ksenofontov A.
dc.contributor.author Bichan N.
dc.contributor.author Khodov I.
dc.contributor.author Antina E.
dc.contributor.author Berezin M.
dc.contributor.author Vyugin A.
dc.date.accessioned 2019-01-22T20:35:42Z
dc.date.available 2019-01-22T20:35:42Z
dc.date.issued 2018
dc.identifier.issn 0167-7322
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/147875
dc.description.abstract © 2018 Elsevier B.V. This paper presents the results of UV/vis, fluorescence, FT-IR, DOSY, and DFT study of a novel non-covalent supramolecular systems based on zinc(II) bis(dipyrromethenate)s ([Zn2L2]) with C60. It was found that zinc(II) bis(dipyrromethenate) forms stable supramolecular π-π-complexes ([Zn2L2(C60)4]) with C60. DFT calculations revealed stable complexation between [Zn2L2] and C60. The [Zn2L2(C60)4] LUMO energy levels are predominantly spread on the C60 unit and the HOMO energy levels are mainly spread on the [Zn2L2]. The photoinduced electron transfer testing by the substantial fluorescence quenching of the [Zn2L2] by non-covalent bonded C60 gives the positive result that shows prospects of the studying [Zn2L2(C60)4] as the active layers in solar energy conversion devices.
dc.relation.ispartofseries Journal of Molecular Liquids
dc.subject Fluorescence
dc.subject Fullerenes
dc.subject Non-covalent
dc.subject Supramolecular systems
dc.subject Zinc(II) bis(dipyrromethenate)s
dc.title Novel non-covalent supramolecular systems based on zinc(II) bis(dipyrromethenate)s with fullerenes
dc.type Article
dc.relation.ispartofseries-volume 269
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 327
dc.source.id SCOPUS01677322-2018-269-SID85051404787


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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