The first molybdenum oxo-iodide cluster – [mo<inf>4</inf>oi<inf>12</inf>]<sup>2–</sup>

dc.date.accessioned	2019-01-22T20:35:03Z
dc.date.available	2019-01-22T20:35:03Z
dc.date.issued	2018
dc.identifier.issn	0044-2313
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/147821
dc.description.abstract	© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Reaction of Mo(CO)6 with Bu4NI and I2 in diglyme yielded a new butterfly MoIII cluster [Mo4OI12]2–. The structure of tetraphen-ylphosphonium salt was determined by X-ray single crystal diffraction. Ph4P+ and Bu4N+ salts were further characterized by elemental analy-sis, mass spectrometry, energy-dispersive X-ray (EDX), IR, Raman, and UV/Vis spectroscopy and CVA studies. The cluster anion has a butterfly array of molybdenum atoms and can be represented as [Mo4(μ4-O)(μ3-I)2(μ2-I4)I6]2–.
dc.relation.ispartofseries	Zeitschrift fur Anorganische und Allgemeine Chemie
dc.subject	Butterfly-type core
dc.subject	Electrochemistry
dc.subject	Molybdenum
dc.subject	Molybdenum iodide cluster
dc.subject	Structure
dc.subject	Synthesis
dc.title	The first molybdenum oxo-iodide cluster – [mo<inf>4</inf>oi<inf>12</inf>]<sup>2–</sup>
dc.type	Article
dc.relation.ispartofseries-issue	8-9
dc.relation.ispartofseries-volume	644
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	438
dc.source.id	SCOPUS00442313-2018-644-89-SID85054688763

Files in this item

Size: 49.87Kb

Format: PDF

Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.