Structure and Luminescent Properties of Cluster Complexes with the {Mo<inf>6</inf>(μ<inf>3</inf>-SeCl<inf>7</inf>)}<sup>3+</sup> Core

dc.date.accessioned	2019-01-22T20:33:16Z
dc.date.available	2019-01-22T20:33:16Z
dc.date.issued	2018
dc.identifier.issn	0022-4766
dc.identifier.uri	https://dspace.kpfu.ru/xmlui/handle/net/147686
dc.description.abstract	© 2018, Pleiades Publishing, Ltd. The selenium atom substitution for one of the capping chloride ligands in [Mo6(μ3-Cl8)Cl6]2– under the action of H2Se in situ results in a [Mo6(μ3-SeCl7)Cl6]3– cluster which is isolated and structurally characterized in the form of (Bu4N)3[Mo6(μ3-SeCl7)Cl6] (I). In the acetonitrile solution the complex exhibits luminescence (λmax = 775 nm, τem = 1.8 μs, Φem = 0.004). When the solution of I in acetonitrile is heated, a partial solvolysis product of the composition (Bu4N)2[Mo6(μ3-SeCl7)Cl5(CH3CN)] (II) is isolated and structurally characterized.
dc.relation.ispartofseries	Journal of Structural Chemistry
dc.subject	crystal structure
dc.subject	luminescence
dc.subject	molybdenum cluster complexes
dc.subject	solvation
dc.subject	substitution of bridging chloride ligands
dc.subject	synthesis
dc.title	Structure and Luminescent Properties of Cluster Complexes with the {Mo<inf>6</inf>(μ<inf>3</inf>-SeCl<inf>7</inf>)}<sup>3+</sup> Core
dc.type	Article
dc.relation.ispartofseries-issue	1
dc.relation.ispartofseries-volume	59
dc.collection	Публикации сотрудников КФУ
dc.relation.startpage	177
dc.source.id	SCOPUS00224766-2018-59-1-SID85044054353

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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.