dc.contributor.author |
Butenko G. |
|
dc.contributor.author |
Vereshchagin A. |
|
dc.contributor.author |
Remizov A. |
|
dc.contributor.author |
Nurullina R. |
|
dc.date.accessioned |
2018-09-20T20:43:46Z |
|
dc.date.available |
2018-09-20T20:43:46Z |
|
dc.date.issued |
1979 |
|
dc.identifier.issn |
0568-5230 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/146200 |
|
dc.description.abstract |
1. The substituted methylarylsulfonates and arylarylsulfonates exist as mixtures of trans and gauche conformers, the latter predominating at equilibrium (∼70%). 2. The angle of aryl group rotation relative to the Csp3-S-O plane is 43° in the methylphenylsulfonates and the methyl-p-tolylsulfonates and 75° in the methyl-p-bromophenylsulfonates. 3. As a result of electron-acceptor effects from the SO2 group, the S-O-C plane of the arylsulfonic acids esters are almost perpendicular to the aromatic ring. © 1980 Plenum Publishing Corporation. |
|
dc.relation.ispartofseries |
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science |
|
dc.title |
Conformations of the methyl and aryl esters of the arylsulfonic acids |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
8 |
|
dc.relation.ispartofseries-volume |
28 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
1624 |
|
dc.source.id |
SCOPUS05685230-1979-28-8-SID34250268634 |
|