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dc.contributor.author | Butenko G. | |
dc.contributor.author | Vereshchagin A. | |
dc.contributor.author | Remizov A. | |
dc.contributor.author | Nurullina R. | |
dc.date.accessioned | 2018-09-20T20:43:46Z | |
dc.date.available | 2018-09-20T20:43:46Z | |
dc.date.issued | 1979 | |
dc.identifier.issn | 0568-5230 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/146200 | |
dc.description.abstract | 1. The substituted methylarylsulfonates and arylarylsulfonates exist as mixtures of trans and gauche conformers, the latter predominating at equilibrium (∼70%). 2. The angle of aryl group rotation relative to the Csp3-S-O plane is 43° in the methylphenylsulfonates and the methyl-p-tolylsulfonates and 75° in the methyl-p-bromophenylsulfonates. 3. As a result of electron-acceptor effects from the SO2 group, the S-O-C plane of the arylsulfonic acids esters are almost perpendicular to the aromatic ring. © 1980 Plenum Publishing Corporation. | |
dc.relation.ispartofseries | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science | |
dc.title | Conformations of the methyl and aryl esters of the arylsulfonic acids | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 8 | |
dc.relation.ispartofseries-volume | 28 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 1624 | |
dc.source.id | SCOPUS05685230-1979-28-8-SID34250268634 |