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Ionization constants of cyclic derivatives of phosphorus acids in n-propyl alcohol

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dc.contributor.author Ovchinnikov V.
dc.contributor.author Galkin V.
dc.contributor.author Cherkasov R.
dc.contributor.author Pudovik A.
dc.date.accessioned 2018-09-20T20:41:23Z
dc.date.available 2018-09-20T20:41:23Z
dc.date.issued 1977
dc.identifier.issn 0568-5230
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/146178
dc.description.abstract 1. Ionization constants for various types of cyclic phosphorus acids have been determined in abs. n-propanol. The pKa values of these acids are determined by the electronic nature of the dioxyalkylene substituent and the structural singularities of the exocyclic reaction center. 2. Factors affecting the phosphonate-phosphite tautomerism of the cyclic phosphorus acids are suggested. Passage from the phosphonate form of the phosphoric acids to the phosphite is promoted by the acceptor activity of the O-R-O group and the low value of the intracyclic angle at the P atom. © 1978 Plenum Publishing Corporation.
dc.relation.ispartofseries Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
dc.title Ionization constants of cyclic derivatives of phosphorus acids in n-propyl alcohol
dc.type Article
dc.relation.ispartofseries-issue 9
dc.relation.ispartofseries-volume 26
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 1869
dc.source.id SCOPUS05685230-1977-26-9-SID34250300279

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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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