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dc.contributor.author | Ovsyannikov A. | |
dc.contributor.author | Noamane M. | |
dc.contributor.author | Abidi R. | |
dc.contributor.author | Ferlay S. | |
dc.contributor.author | Solovieva S. | |
dc.contributor.author | Antipin I. | |
dc.contributor.author | Konovalov A. | |
dc.contributor.author | Kyritsakas N. | |
dc.contributor.author | Hosseini M. | |
dc.date.accessioned | 2018-09-19T22:18:54Z | |
dc.date.available | 2018-09-19T22:18:54Z | |
dc.date.issued | 2016 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/145011 | |
dc.description.abstract | © The Royal Society of Chemistry 2016.Combinations of six new coordinating tectons (3-8) tetrakis-pyrazolyl appended calix[4]arenes, blocked in 1,3-A conformation, based on 1 (tetrathiacalix[4]arene) and 2 (tetrathiatetramercaptocalix[4]arene) derivatives, with AgX salts (X = NO3-, BF4-, XF6- (X = P, As and Sb)) lead to nine new silver coordination networks. The flexible nature of tectons 3-8 (length of the spacer between the macrocycle and the pyrazolyl coordinating unit), their high number of potential coordinating sites and the loose coordination demand of Ag+ cation lead to the formation of a large variety of networks with different dimensionality: from 1D (5-AgSbF6, 5-AgBF4, 7-AgSbF6 and 8-AgNO3) to extended 2D (6-AgBF4 and 8-AgSbF6) and to a series of three isostructural porous diamond-like 3D architectures (6-AgXF6 (X = P, As and Sb)). | |
dc.title | Molecular tectonics: Dimensionality and geometry control of silver coordination networks based on pyrazolyl appended thiacalixarenes | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 5 | |
dc.relation.ispartofseries-volume | 18 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 691 | |
dc.source.id | SCOPUS-2016-18-5-SID84977121544 |