dc.contributor.author |
Ovsyannikov A. |
|
dc.contributor.author |
Lang M. |
|
dc.contributor.author |
Ferlay S. |
|
dc.contributor.author |
Solovieva S. |
|
dc.contributor.author |
Antipin I. |
|
dc.contributor.author |
Konovalov A. |
|
dc.contributor.author |
Kyritsakas N. |
|
dc.contributor.author |
Hosseini M. |
|
dc.date.accessioned |
2018-09-19T22:18:50Z |
|
dc.date.available |
2018-09-19T22:18:50Z |
|
dc.date.issued |
2016 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/145009 |
|
dc.description.abstract |
© The Royal Society of Chemistry 2016.A series of thiacalix[4]arene derivatives blocked in the 1,3-alternate conformation and bearing four carboxylic acids have been designed and synthesized. These compounds, owing to the H-bond donor (OH moiety) and acceptor (CO group) nature of the carboxylic acid moieties, behave as self-complementary tectons and lead to the formation of tubular 1D H-bonded networks in the crystalline phase. Upon deprotonation of the self-complementary neutral compounds, i.e. transformation of carboxylic acid moieties into carboxylates, anionic tectons are generated. Due to their propensity to form H-bonded networks in the presence of a dicationic H-bond donor tecton of the cyclic bis-amidinium type, designed to behave as a molecular staple interconnecting two carboxylates moieties, 1- and 2-D H-bonded networks are formed under self-assembly conditions. |
|
dc.title |
Molecular tectonics: Tetracarboxythiacalix[4]arene derivatives as tectons for the formation of hydrogen-bonded networks |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
44 |
|
dc.relation.ispartofseries-volume |
18 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
8622 |
|
dc.source.id |
SCOPUS-2016-18-44-SID84994885633 |
|