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dc.contributor.author | Ovsyannikov A. | |
dc.contributor.author | Lang M. | |
dc.contributor.author | Ferlay S. | |
dc.contributor.author | Solovieva S. | |
dc.contributor.author | Antipin I. | |
dc.contributor.author | Konovalov A. | |
dc.contributor.author | Kyritsakas N. | |
dc.contributor.author | Hosseini M. | |
dc.date.accessioned | 2018-09-19T22:18:50Z | |
dc.date.available | 2018-09-19T22:18:50Z | |
dc.date.issued | 2016 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/145009 | |
dc.description.abstract | © The Royal Society of Chemistry 2016.A series of thiacalix[4]arene derivatives blocked in the 1,3-alternate conformation and bearing four carboxylic acids have been designed and synthesized. These compounds, owing to the H-bond donor (OH moiety) and acceptor (CO group) nature of the carboxylic acid moieties, behave as self-complementary tectons and lead to the formation of tubular 1D H-bonded networks in the crystalline phase. Upon deprotonation of the self-complementary neutral compounds, i.e. transformation of carboxylic acid moieties into carboxylates, anionic tectons are generated. Due to their propensity to form H-bonded networks in the presence of a dicationic H-bond donor tecton of the cyclic bis-amidinium type, designed to behave as a molecular staple interconnecting two carboxylates moieties, 1- and 2-D H-bonded networks are formed under self-assembly conditions. | |
dc.title | Molecular tectonics: Tetracarboxythiacalix[4]arene derivatives as tectons for the formation of hydrogen-bonded networks | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 44 | |
dc.relation.ispartofseries-volume | 18 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 8622 | |
dc.source.id | SCOPUS-2016-18-44-SID84994885633 |