| dc.contributor.author |
Ivanova T. |
|
| dc.contributor.author |
Turanova O. |
|
| dc.contributor.author |
Mingalieva L. |
|
| dc.contributor.author |
Gilmutdinov I. |
|
| dc.contributor.author |
Ovchinnikov I. |
|
| dc.date.accessioned |
2018-09-19T22:18:35Z |
|
| dc.date.available |
2018-09-19T22:18:35Z |
|
| dc.date.issued |
2016 |
|
| dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/145001 |
|
| dc.description.abstract |
© Kazan Federal University (KFU).[Fe(3-MeO-Qsal)2]Y (Y = PF6, BF4, NCS, NO3, BPh4) compounds were synthesized using the diffusion method and studied by the electron spin resonance and the magnetic susceptibility methods in the temperature range (5-300) K. Coexistence of spatially separated high-spin and low-spin fractions in these compounds was observed. Low-spin fraction of all compounds reveals the antiferromagnetic correlations at low temperatures. High-spin fraction of complexes with Y = PF6 demonstrate the weak ferromagnetic properties due to exchange interaction between complexes in whole temperature range. Influence of outer-sphere anion on the spin state, the electronic properties of low-spin Fe(III) complexes is demonstrated. |
|
| dc.subject |
High-spin and low-spin state |
|
| dc.subject |
Intermolecular interactions |
|
| dc.subject |
Outer-sphere anions |
|
| dc.title |
Electronic and magnetic properties of [Fe(3-MeO-Qsal)2]y•n solvent (n = 0,1) complexes |
|
| dc.type |
Article |
|
| dc.relation.ispartofseries-issue |
1 |
|
| dc.relation.ispartofseries-volume |
18 |
|
| dc.collection |
Публикации сотрудников КФУ |
|
| dc.source.id |
SCOPUS-2016-18-1-SID85006337640 |
|