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Thermochemistry of Pyridinium Based Ionic Liquids with Tetrafluoroborate Anion
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| dc.contributor.author | Zaitsau D. | |
| dc.contributor.author | Yermalayeu A. | |
| dc.contributor.author | Emel'yanenko V. | |
| dc.contributor.author | Schulz A. | |
| dc.contributor.author | Verevkin S. | |
| dc.date.accessioned | 2018-09-19T22:01:21Z | |
| dc.date.available | 2018-09-19T22:01:21Z | |
| dc.date.issued | 2017 | |
| dc.identifier.issn | 0044-2313 | |
| dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/144598 | |
| dc.description.abstract | © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, WeinheimEnthalpies of vaporization of five pyridinium based ionic liquids (ILs): 1-R-pyridinium (with R = ethyl, butyl-, and hexyl), 1-butyl-3-methyl-pyridinium, and 1-butyl-4-methyl-pyridinium with tetrafluoroborate anion were studied using Quartz Crystal Microbalance (QCM). Enthalpies of solution of these ionic liquids were measured by high-precision solution calorimetry. Gas-phase enthalpies of formation of ILs were calculated by using the high-level quantum-chemical method G3MP2. From combination of experimental and theoretical results, enthalpies of formation of aqueous pyridinium based cations were derived for the first time. | |
| dc.relation.ispartofseries | Zeitschrift fur Anorganische und Allgemeine Chemie | |
| dc.subject | Ionic liquids; Enthalpy of vaporization; Quartz Crystal Microbalance (QCM); Solution calorimetry; Quantum chemical calculations | |
| dc.title | Thermochemistry of Pyridinium Based Ionic Liquids with Tetrafluoroborate Anion | |
| dc.type | Article | |
| dc.relation.ispartofseries-issue | 1 | |
| dc.relation.ispartofseries-volume | 643 | |
| dc.collection | Публикации сотрудников КФУ | |
| dc.relation.startpage | 87 | |
| dc.source.id | SCOPUS00442313-2017-643-1-SID85001052509 |
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Публикации сотрудников КФУ Scopus [24551]
Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.