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dc.contributor.author | Yermalayeu A. | |
dc.contributor.author | Zaitsau D. | |
dc.contributor.author | Loor M. | |
dc.contributor.author | Schaumann J. | |
dc.contributor.author | Emel'yanenko V. | |
dc.contributor.author | Schulz S. | |
dc.contributor.author | Verevkin S. | |
dc.date.accessioned | 2018-09-19T22:01:19Z | |
dc.date.available | 2018-09-19T22:01:19Z | |
dc.date.issued | 2017 | |
dc.identifier.issn | 0044-2313 | |
dc.identifier.uri | https://dspace.kpfu.ru/xmlui/handle/net/144597 | |
dc.description.abstract | © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, WeinheimThe vaporization thermodynamics of symmetric imidazolium based ionic liquids of the general formula [CnCnIm][Br] with the chains length n = 4, 5, 6, and 8 were investigated using a combination of DSC, TGA, and QCM methods with quantum chemical calculations. Comparison of vaporization enthalpies for the symmetric ([CnCnIm][Br]) and asymmetric imidazolium based ILs ([Cnmim][Br]) revealed a general trend with the lower vaporization enthalpies of the symmetric species indicating a significant decrease of the Coulombic interactions affecting energetics of vaporization. | |
dc.relation.ispartofseries | Zeitschrift fur Anorganische und Allgemeine Chemie | |
dc.subject | Ionic liquids; Enthalpy of vaporization; Thermogravimetry; Quartz-crystal microbalance; Quantum chemical calculations | |
dc.title | Imidazolium Based Ionic Liquids: Impact of the Cation Symmetry and Alkyl Chain Length on the Enthalpy of Vaporization | |
dc.type | Article | |
dc.relation.ispartofseries-issue | 1 | |
dc.relation.ispartofseries-volume | 643 | |
dc.collection | Публикации сотрудников КФУ | |
dc.relation.startpage | 81 | |
dc.source.id | SCOPUS00442313-2017-643-1-SID85001018568 |