dc.contributor.author |
Yermalayeu A. |
|
dc.contributor.author |
Zaitsau D. |
|
dc.contributor.author |
Loor M. |
|
dc.contributor.author |
Schaumann J. |
|
dc.contributor.author |
Emel'yanenko V. |
|
dc.contributor.author |
Schulz S. |
|
dc.contributor.author |
Verevkin S. |
|
dc.date.accessioned |
2018-09-19T22:01:19Z |
|
dc.date.available |
2018-09-19T22:01:19Z |
|
dc.date.issued |
2017 |
|
dc.identifier.issn |
0044-2313 |
|
dc.identifier.uri |
https://dspace.kpfu.ru/xmlui/handle/net/144597 |
|
dc.description.abstract |
© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, WeinheimThe vaporization thermodynamics of symmetric imidazolium based ionic liquids of the general formula [CnCnIm][Br] with the chains length n = 4, 5, 6, and 8 were investigated using a combination of DSC, TGA, and QCM methods with quantum chemical calculations. Comparison of vaporization enthalpies for the symmetric ([CnCnIm][Br]) and asymmetric imidazolium based ILs ([Cnmim][Br]) revealed a general trend with the lower vaporization enthalpies of the symmetric species indicating a significant decrease of the Coulombic interactions affecting energetics of vaporization. |
|
dc.relation.ispartofseries |
Zeitschrift fur Anorganische und Allgemeine Chemie |
|
dc.subject |
Ionic liquids; Enthalpy of vaporization; Thermogravimetry; Quartz-crystal microbalance; Quantum chemical calculations |
|
dc.title |
Imidazolium Based Ionic Liquids: Impact of the Cation Symmetry and Alkyl Chain Length on the Enthalpy of Vaporization |
|
dc.type |
Article |
|
dc.relation.ispartofseries-issue |
1 |
|
dc.relation.ispartofseries-volume |
643 |
|
dc.collection |
Публикации сотрудников КФУ |
|
dc.relation.startpage |
81 |
|
dc.source.id |
SCOPUS00442313-2017-643-1-SID85001018568 |
|