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Six-membered ring aliphatic compounds: A search for regularities in phase transitions

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dc.contributor.author Nagrimanov R.
dc.contributor.author Solomonov B.
dc.contributor.author Emel'yanenko V.
dc.contributor.author Verevkin S.
dc.date.accessioned 2018-09-19T22:00:34Z
dc.date.available 2018-09-19T22:00:34Z
dc.date.issued 2016
dc.identifier.issn 0040-6031
dc.identifier.uri https://dspace.kpfu.ru/xmlui/handle/net/144585
dc.description.abstract © 2016 Elsevier B.V.Absolute vapor pressures of 1-Cl-adamantane, 2-Cl-adamantane, 1-Br-adamantane, 2-Br-adamantane, as well as of Br-cyclohexane were measured by using the transpiration method. Standard molar enthalpies of sublimation of halogen substituted adamantanes at 298.15 K were derived from vapor pressure temperature dependences. Standard molar enthalpies of solution of adamantane and halogen adamantanes in cyclohexane were measured with a high-precision solution calorimeter. A theoretical procedure based on the solution calorimetry was applied to derive sublimation enthalpies of halogen adamantanes independently. Molar enthalpies of fusion were measured with help of DSC. The consistent data set of phase transitions for each compound was evaluated and used for discussion of structure-property relations in adamantane and cyclohexane derivatives. A simple way to predict enthalpies of vaporization of compounds containing six-membered rings was suggested for practical thermochemical calculations.
dc.relation.ispartofseries Thermochimica Acta
dc.subject Adamantane derivatives
dc.subject Enthalpies of phase transitions
dc.subject Solution calorimetry
dc.subject Transpiration method
dc.subject Vapor pressure
dc.title Six-membered ring aliphatic compounds: A search for regularities in phase transitions
dc.type Article
dc.relation.ispartofseries-volume 638
dc.collection Публикации сотрудников КФУ
dc.relation.startpage 80
dc.source.id SCOPUS00406031-2016-638-SID84977100238


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  • Публикации сотрудников КФУ Scopus [24551]
    Коллекция содержит публикации сотрудников Казанского федерального (до 2010 года Казанского государственного) университета, проиндексированные в БД Scopus, начиная с 1970г.

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